Remoción de níquel del sistema Ni(II)-NH3-CO2-SO2-H2O por electrocoagulación a escala de banco. Parte II
Resumo
Se estudió la remoción de níquel del sistema Ni(II)-NH3-CO2-SO2-H2O por electrocoagulación en un reactor cilíndrico con agitación de 25 L de capacidad útil y dos pares de electrodos Al/Al. Se procesó licor efluente del proceso de destilación de la planta productora de níquel en Punta Gorda, Cuba, con una concentración de níquel de 300 a 652 mg/L, a una densidad de corriente de 8,3 mA/cm2, 60 ºC y pH 8,64 (+/-0,033). Se obtuvo una eficiencia de remoción promedio de 99,65 (+/-0,07) %, concentración en equilibrio menor que 2 mg/Ly capacidad de adsorción entre 3342 y 7264 mg/g. De acuerdo al análisis cinético y de equilibrio, se considera que el proceso está probablemente bajo el control de la resistencia de los mecanismos reacción química y su contribución autocatalítica. El costo de operación por consumo de energía eléctrica y de electrodo fue 11,12 y 16,02 CUP/kg de Ni y el consumo específico de energía de 1,709 a 2,342 kW-h/kg de Al.
Referências
1. VLACHOU, M., et al. Effect of various parameters in removing Cr and Ni from model wastewater by using electrocoagulation. Global NEST J.[en línea]. 2013, 15(4). 494-503. ISSN: 2241-777X.
2. SABEDOT-PERTILE, T., JONKO, E. Treatment of hydrocyanic galvanic effluent by electrocoagulation. Korean J ChemEng[en línea]. 2017, 34(10). ISSN: 1975-7220. DOI: 10.1007/s11814-017-0178-y
3. SHUNXI-ZHANG, XIAOHONG-YANG, et al. Treatment of wastewater containing nickel by electrocoagulation. Environ. Eng. Sci.[en línea]. 2017,34(12). 861–871. ISSN: 1557-9018, DOI: 10.1089/ees.2016.0621
4. BEYAZIT, N. Copper (II), Chromium (VI) and Nickel (II) Removal from Metal Plating Effluent by Electrocoagulation. Int. J. Electrochem. Sci.[en línea]. 2014, 9(8). 4315 – 4330. ISSN: 1452-3981.
5. LEKHLIF, B., OUDRHIRI, L., ZIDANE, F., et al. Study of the electrocoagulation of electroplating industry wastewaters charged by nickel (II) and chromium (VI). J. Mater. Environ. Sci. 2014, 5(1). 111-120. ISSN: 2028-2508.
6. KALEEM, M. K, et al. Efficiency of Aluminum and Iron Electrodes for the Removal of Heavy Metals by Electrocoagulation Method. J. Korean Chem. Soc.[en línea]. 2013, 57(3). 316-321. ISSN: 1229-5949. DOI: 10.5012/jkcs.2013.57.3.316
7.MANSOUR, S. E; HASIEB, I. H. Removal of Nickel from drinking water by electrocoagulation technique using alternating current. Curr. Res. Chem.[en línea]. 2012, 4(2). 41-50. ISSN: 2348-5221. DOI: 10.3923/crc.2012.41.50
8. AL‑QODAH, Z., AL‑SHANNAG, M. Heavy metal ions removal from wastewater using electrocoagulation processes. Sep. Sci. Technol. [en línea]. 2017, 52(17). 2649-2676. ISSN: 1520-5754. DOI: 10.1080/01496395.2017.1373677
9. ROJAS-VARGAS, A., et al. Lixiviación carbonato amoniacal: estimación del níquel disuelto en el efluente de destilación. Revista de Metalurgia [en línea]. 2019, 55(3). 1-11. ISSN-L: 0034-8570. DOI: 10.3989/revmetalm.149
10.ROJAS-VARGAS, A., RICARDO-RIVERON, et al. Remoción de níquel por electrocoagulación del sistema Ni(II)-NH3-CO2-SO2-H2O con electrodos de aluminio. Tecnología Química[en línea]. 2020, 40(2). ISSN: 2224-6185.
11. NARIYAN, E., SILLANPÄÄ, M., et al. Electrocoagulation treatment of mine water from the deepest working European metal mine - Performance, isotherm and kinetic studies. Sep. Purif. Technol. 2017, 177, 363–373. e-ISSN: 1383-5866. DOI: 10.1016/j.seppur.2016.12.042
12. INYINBOR A.A., ADEKOLA, F.A., OLATUNJI, G.A. Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of RhodamineBdye on to Raphiahookerie fruit epicarp. Water Resources and Industry. 2016, 15. 14–27.e-ISSN: 2212-3717.DOI: 10.1016/j.wri.2016.06.001
13. IDOWU-ADEOGUN, A., BABU-BALAKRISHNAN, R. Kinetics, isothermal and thermodynamics studies of electrocoagulation removal of dye rhodamine B. Appl Water Sci.2015.e-ISSN: 2190-5495. DOI: 10.1007/s13201-015-0337-4
14. ÇIRIĞ, N.S., KUBILAY, Ş., SAVRAN, A., et al. Kinetics and Thermodynamic Studies of Adsorption of Methylene Blue. IOSR-JAC, [en línea]. 2017, 10(5). 53-63. ISSN: 2278-5736. DOI: 10.9790/5736-1005015363
15. KAMARAJ, R., GANESAN, P., VASUDEVAN, S. Removal of lead from aqueous solutions by electrocoagulation: isotherm, kinetics and thermodynamic studies. Int. J. Environ. Sci. Technol. 2015, 12. 683–692. e-ISSN: 1735-1472. DOI: 10.1007/s13762-013-0457-z
16. YOOSEFIAN, M., AHMADZADEH, S., AGHASI, M., et al. Optimization of electrocoagulation process for efficient removal of ciprofloxacin antibiotic using iron electrode; kinetic and isotherm studies of adsorption. J. Mol. Liq. 2016. DOI: 10.1016/j.molliq.2016.11.093
17. AYAWEI, N., EBELEGI, A.N., WANKASI, D. Modelling and Interpretation of Adsorption Isotherms.J. Chem-NY. 2017. ISSN: 2090-9071. DOI: 10.1155/2017/3039817
18. YUTINAN-QIAN. Explore adsorption comprenssion using computational and experimental methods. [Johns Hopkins University]. (Thesis for the degree of Master of Science), 2019.
19. RISA-VIEIRA, A. Surface complexation modeling of Pb(II), Cd(II) and Sc(II) onto iron Hydroxide in single a bisolute systems. [University of Texas Austin]. (Thesis for the degree of Doctor of Philosophy), 2006.
20. PILON, L., WANG, H., D’ENTREMONT, A. Recent Advances in Continuum Modeling of Interfacial and Transport Phenomena in Electric Double Layer Capacitors. J. Electroch. Soc., 2015, 162(5). A5158-A5178.ISSN. 0013-4651
21. PINZÓN, B. M.L., VERA, V.L.E. Cinética de bioadsorción de Cr (III) usando cáscara de naranja. Dyna.2009, 160, 95-106. ISSN 0012-7353.
22. QINGWEN-HE. Investigation of stabilization mechanisms for colloidal suspension using nanoparticles. [University of Louisville]. (Thesis for the degree of Doctor of Philosophy), 2014.
23. STUMM-WERNER. The Inner-Sphere Surface Complex. A Key to Understanding Surface Reactivity. 1995, J. Am. Chem. Soc. ID: 0065-2393/95/0244-0001$09.28/0.
24. SABÍN, F.J.D. Estabilidad coloidal de nanoestructuras liposómicas. [Universidad de Santiago de Compostela]. (Tesis Doctoral), 2007.
2. SABEDOT-PERTILE, T., JONKO, E. Treatment of hydrocyanic galvanic effluent by electrocoagulation. Korean J ChemEng[en línea]. 2017, 34(10). ISSN: 1975-7220. DOI: 10.1007/s11814-017-0178-y
3. SHUNXI-ZHANG, XIAOHONG-YANG, et al. Treatment of wastewater containing nickel by electrocoagulation. Environ. Eng. Sci.[en línea]. 2017,34(12). 861–871. ISSN: 1557-9018, DOI: 10.1089/ees.2016.0621
4. BEYAZIT, N. Copper (II), Chromium (VI) and Nickel (II) Removal from Metal Plating Effluent by Electrocoagulation. Int. J. Electrochem. Sci.[en línea]. 2014, 9(8). 4315 – 4330. ISSN: 1452-3981.
5. LEKHLIF, B., OUDRHIRI, L., ZIDANE, F., et al. Study of the electrocoagulation of electroplating industry wastewaters charged by nickel (II) and chromium (VI). J. Mater. Environ. Sci. 2014, 5(1). 111-120. ISSN: 2028-2508.
6. KALEEM, M. K, et al. Efficiency of Aluminum and Iron Electrodes for the Removal of Heavy Metals by Electrocoagulation Method. J. Korean Chem. Soc.[en línea]. 2013, 57(3). 316-321. ISSN: 1229-5949. DOI: 10.5012/jkcs.2013.57.3.316
7.MANSOUR, S. E; HASIEB, I. H. Removal of Nickel from drinking water by electrocoagulation technique using alternating current. Curr. Res. Chem.[en línea]. 2012, 4(2). 41-50. ISSN: 2348-5221. DOI: 10.3923/crc.2012.41.50
8. AL‑QODAH, Z., AL‑SHANNAG, M. Heavy metal ions removal from wastewater using electrocoagulation processes. Sep. Sci. Technol. [en línea]. 2017, 52(17). 2649-2676. ISSN: 1520-5754. DOI: 10.1080/01496395.2017.1373677
9. ROJAS-VARGAS, A., et al. Lixiviación carbonato amoniacal: estimación del níquel disuelto en el efluente de destilación. Revista de Metalurgia [en línea]. 2019, 55(3). 1-11. ISSN-L: 0034-8570. DOI: 10.3989/revmetalm.149
10.ROJAS-VARGAS, A., RICARDO-RIVERON, et al. Remoción de níquel por electrocoagulación del sistema Ni(II)-NH3-CO2-SO2-H2O con electrodos de aluminio. Tecnología Química[en línea]. 2020, 40(2). ISSN: 2224-6185.
11. NARIYAN, E., SILLANPÄÄ, M., et al. Electrocoagulation treatment of mine water from the deepest working European metal mine - Performance, isotherm and kinetic studies. Sep. Purif. Technol. 2017, 177, 363–373. e-ISSN: 1383-5866. DOI: 10.1016/j.seppur.2016.12.042
12. INYINBOR A.A., ADEKOLA, F.A., OLATUNJI, G.A. Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of RhodamineBdye on to Raphiahookerie fruit epicarp. Water Resources and Industry. 2016, 15. 14–27.e-ISSN: 2212-3717.DOI: 10.1016/j.wri.2016.06.001
13. IDOWU-ADEOGUN, A., BABU-BALAKRISHNAN, R. Kinetics, isothermal and thermodynamics studies of electrocoagulation removal of dye rhodamine B. Appl Water Sci.2015.e-ISSN: 2190-5495. DOI: 10.1007/s13201-015-0337-4
14. ÇIRIĞ, N.S., KUBILAY, Ş., SAVRAN, A., et al. Kinetics and Thermodynamic Studies of Adsorption of Methylene Blue. IOSR-JAC, [en línea]. 2017, 10(5). 53-63. ISSN: 2278-5736. DOI: 10.9790/5736-1005015363
15. KAMARAJ, R., GANESAN, P., VASUDEVAN, S. Removal of lead from aqueous solutions by electrocoagulation: isotherm, kinetics and thermodynamic studies. Int. J. Environ. Sci. Technol. 2015, 12. 683–692. e-ISSN: 1735-1472. DOI: 10.1007/s13762-013-0457-z
16. YOOSEFIAN, M., AHMADZADEH, S., AGHASI, M., et al. Optimization of electrocoagulation process for efficient removal of ciprofloxacin antibiotic using iron electrode; kinetic and isotherm studies of adsorption. J. Mol. Liq. 2016. DOI: 10.1016/j.molliq.2016.11.093
17. AYAWEI, N., EBELEGI, A.N., WANKASI, D. Modelling and Interpretation of Adsorption Isotherms.J. Chem-NY. 2017. ISSN: 2090-9071. DOI: 10.1155/2017/3039817
18. YUTINAN-QIAN. Explore adsorption comprenssion using computational and experimental methods. [Johns Hopkins University]. (Thesis for the degree of Master of Science), 2019.
19. RISA-VIEIRA, A. Surface complexation modeling of Pb(II), Cd(II) and Sc(II) onto iron Hydroxide in single a bisolute systems. [University of Texas Austin]. (Thesis for the degree of Doctor of Philosophy), 2006.
20. PILON, L., WANG, H., D’ENTREMONT, A. Recent Advances in Continuum Modeling of Interfacial and Transport Phenomena in Electric Double Layer Capacitors. J. Electroch. Soc., 2015, 162(5). A5158-A5178.ISSN. 0013-4651
21. PINZÓN, B. M.L., VERA, V.L.E. Cinética de bioadsorción de Cr (III) usando cáscara de naranja. Dyna.2009, 160, 95-106. ISSN 0012-7353.
22. QINGWEN-HE. Investigation of stabilization mechanisms for colloidal suspension using nanoparticles. [University of Louisville]. (Thesis for the degree of Doctor of Philosophy), 2014.
23. STUMM-WERNER. The Inner-Sphere Surface Complex. A Key to Understanding Surface Reactivity. 1995, J. Am. Chem. Soc. ID: 0065-2393/95/0244-0001$09.28/0.
24. SABÍN, F.J.D. Estabilidad coloidal de nanoestructuras liposómicas. [Universidad de Santiago de Compostela]. (Tesis Doctoral), 2007.
Publicado
2023-01-05
Como Citar
Rojas-Vargas, A., Magaña-Haynes, M. E., Toro-Alvarez, D. D., & Sánchez-Guillen, C. (2023). Remoción de níquel del sistema Ni(II)-NH3-CO2-SO2-H2O por electrocoagulación a escala de banco. Parte II. Tecnologia Química, 43(1), 121-137. Recuperado de https://tecnologiaquimica.uo.edu.cu/index.php/tq/article/view/5313
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