Nickel removing of the system Ni(II)-NH3-CO2-SO2-H2O by electrocoagulation on an bank scale. Part I
Keywords:
kinetic; electrocoagulation; nickel.
Abstract
The nickel removal from the Ni(II)-NH3-CO2-SO2-H2O system was studied by bench-scale electrocoagulation in a stirred cylindrical reactor, with a useful capacity of 25 L and two pairs of Al/Al electrodes. Effluent liquor from the distillation process of the nickel-producer plant in Punta Gorda, Cuba, and synthetic liquor prepared in the laboratory was used. The operating parameters were: pH 8,6, density of current 8,3 mA/cm2, 40 min of electrolysis, 60 ºC and initial concentration of dissolved nickel between 300 and 652 mg/L. An average removal efficiency of 99,67 (+/-0,06) % was obtained for the effluent liquor, resulting a maximum equilibrium concentration of 7 mg/L. The analysis of the reaction kinetics suggests that the removal is determined by the simultaneous contribution of the resistance of the mechanisms: nucleation, external diffusion, the chemical reaction and a possible autocatalytic effect by the Roginskii-Shultz equation.
References
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2. NEPO, N.J., GOURICH, B., et al. Electrocoagulation process in water treatment: A review of electrocoagulation modeling. Desalination [en línea]. 2017, 404. 1–21. ISSN: 0011-9164. DOI:10.1016/j.desal.2016.10.011
3. MAGAÑA-IRONS, L., ROJAS-VARGAS, A., et al. Remoción de contaminantes del residual lácteo por electrocoagulación con electrodos de aluminio. Tecnología Química [en línea]. 2020, 40(1). 19-36. ISSN: 2224-6185. DOI:10.1590/2224-6185.2020.1.%25x
4. YASIR-ALJABERI, F., MOHAMMEDB, W.T. Analyzing the removal of lead from synthesis wastewater by electrocoagulation technique using experimental design. Desalination and Water Treatment. [en línea]. 2018, 111. 286-296. ISSN: 1944-3986. DOI:10.5004/dwt.2018.22208
5. DIDAR, S.M. Electrocoagulation (EC) technology for wastewater treatment and pollutants removal. Sustain. Water. Resour. Manag. [en línea]. 2017, 5(1). 359-380. ISSN: 2363-5045. DOI:10.1007/s40899-017-0152-1
6. GARCÍA-SEGURA, A., et al. Electrocoagulation and advanced electrocoagulation processes: A general review about the fundamentals, emerging applications. J. Electroanal. Chem. [en línea]. 2017, 801. 267–299. ISSN: 1572-6657. DOI:10.1016/j.jelechem.2017.07.047
7. AL‑QODAH, Z., AL‑SHANNAG, M. Heavy metal ions removal from wastewater using electrocoagulation processes. Sep. Sci. Technol. [en línea]. 2017, 52(17). 2649-2676. ISSN: 1520-5754. DOI:10.1080/01496395.2017.1373677
8. VLACHOU, M., et al. Effect of various parameters in removing Cr and Ni from model wastewater by using electrocoagulation. Global NEST J. [en línea]. 2013, 15(4). 494-503. ISSN: 2241-777X.
9. DERMENTZIS, K., VALSAMIDOU, E., LAZARIDOU, A. Nickel removal from wastewater by electrocoagulation. J. Eng. Sci. Tech. Rev. [en línea]. 2011, 4(2). 188-192. ISSN: 1791-2377. DOI:10.25103/jestr.042.12.
10. ROJAS-VARGAS, A., RICARDO-RIVERON, et al. Remoción de níquel por electrocoagulación del sistema Ni(II)-NH3-CO2-SO2-H2O con electrodos de aluminio. Tecnología Química [en línea]. 2020, 40(2). ISSN: 2224-6185.
11. SABEDOT-PERTILE, T., JONKO, E. Treatment of hydrocyanic galvanic effluent by electrocoagulation: Optimization of operating parameters. Korean J Chem Eng [en línea]. 2017, 34(10). ISSN: 1975-7220. DOI:10.1007/s11814-017- 0178-y
12. SHUNXI ZHANG, XIAOHONG YANG, QUNPENG CHENG. Treatment of Wastewater Containing Nickel by Electrocoagulation Process. Environ. Eng. Sci. [en línea]. 2017, 34(12). 861–871. ISSN: 1557-9018, DOI:10.1089/ees.2016.0621
13. BEYAZIT, N. Copper (II), Chromium (VI) and Nickel (II) Removal from Metal Plating Effluent by Electrocoagulation. Int. J. Electrochem. Sci. [en línea]. 2014, 9(8). 4315 – 4330. ISSN: 1452-3981.
14. LEKHLIF, B., OUDRHIRI, L., ZIDANE, F., et al. Study of the electrocoagulation of electroplating industry wastewaters charged by nickel (II) and chromium (VI). J. Mater. Environ. Sci. 2014, 5(1). 111-120. ISSN: 2028-2508.
15. KALEEM, M. K, et al. Efficiency of Aluminum and Iron Electrodes for the Removal of Heavy Metals [(Ni (II), Pb (II), Cd (II)] by Electrocoagulation Method. J. Korean Chem. Soc. [en línea]. 2013, 57(3). 316-321. ISSN: 1229-5949. DOI: 10.5012/jkcs.2013.57.3.316.
16. MANSOUR, S. E; HASIEB, I. H. Removal of Nickel from drinking water by electrocoagulation technique using alternating current. Curr. Res. Chem. [en línea]. 2012, 4(2). 41-50. ISSN: 2348-5221. DOI: 10.3923/crc.2012.41.50
17. ROJAS-VARGAS, A., at al. Medición del pH durante la destilación del licor producto del proceso Caron (III). Tecnología Química [en línea]. 2012, 32(2). 177-185. ISSN: 2224-6185. DOI:10.1590/2224-6185.2012.2.%25x
18. ROJAS-VARGAS, A., et al. Lixiviación carbonato amoniacal: estimación del níquel disuelto en el efluente de destilación. Revista de Metalurgia [en línea]. 2019, 55(3). 1-11. ISSN-L: 0034-8570. DOI:10.3989/revmetalm.149
19. VASUDEVAN, S., LAKSHMI, J., SOZHAN, G. Simultaneous removal of Co, Cu, and Cr from water. Toxicol. Environ. Chem. [en línea]. 2012, 94(10). 1930-1940. ISSN: 1029-0486. DOI:10.1080/02772248.2012.742898
20. IDOWU-ADEOGUN, A.; BABU-BALAKRISHNAN, R. Kinetics, isothermal and thermodynamics studies of electrocoagulation removal of basic dye rhodamine B from aqueous solution using steel electrodes. Appl Water Sci, [en línea]. 2017, 7. 1711-1723. ISSN: 2190-5495. DOI 10.1007/s13201-015-0337-4.
21. ROMERO, M. M. R. Expresiones analíticas de los modelos cinéticos para la reducción a temperatura programada en la ecuación generalizada de kissinger. Minería y Geología, [en línea]. 2004, 78-86. ISSN: 1993-8012.
22. CANTOS, G.M.A. et. al. Guachapelí contra Marabú y la cinética de sus pirólisis. Rev. Cubana Quím. [en línea]. 2017, 29(3). 362-378, e-ISSN: 2224-5421.
23. LUO SHI YONG, et al. Computer prediction on solid / solid reaction kinetic. Trans. Nonferrous Met. Soc. China. [en línea]. 2001. 11(3), 466-470. ISSN: 1003-6326. DOI: 1003-6326(2001) 03-0466-05.
Published
2022-01-05
How to Cite
Rojas-Vargas, A., Ricardo-Riverón, A., Magaña-Haynes, M. E., Toro-Alvarez, D. D., & Sánchez-Guillen, C. (2022). Nickel removing of the system Ni(II)-NH3-CO2-SO2-H2O by electrocoagulation on an bank scale. Part I. Chemical Technology, 42(1), 114-130. Retrieved from https://tecnologiaquimica.uo.edu.cu/index.php/tq/article/view/5227
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